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@article{Albinati2010,
abstract = {The CuI catalyzed dehydro-halogenation of 1′,1”’-diethynylbiferrocene and Pt(3)Cl Pt(3) = Pt(3)(mu-PBu(t)(2))(3)(CO)(2) (1:2 molar ratio) in diethylamine gives in high yields the bicluster derivative Pt(3)CC-(eta(5)-C(5)H(4))Fe(eta(5)-C(5)H(4))(2), 3, in which two platinum triangles are connected by a diethynylbiferrocene spacer. In the structure of 3, confirmed by a diffractometric study, the two Pt(3) fragments lie, perfectly eclipsed, on the same side of the biferrocenyl moiety; this folded structure is also preferred in solution, as suggested by NMR Diffusion Ordered Spectroscopy (DOSY) and 1D Rotating-frame Overhauser Enhancement (ROE) measurements. Compound 3 exhibits a rich redox behavior, with a crowded sequence of six one-electron oxidation processes, the electrode potentials of which have been evaluated by digital simulations. On the basis of a spectroelectrochemical study, the first two oxidations are assigned to the iron centers of the diferrocenyl unit and the subsequent four electrons are removed from the Pt(3) units.},
author = {Albinati, Alberto and Balzano, Federica and {Fabrizi De Biani}, Fabrizia and Leoni, Piero and Manca, Gabriele and Marchetti, Lorella and Rizzato, Silvia and {Uccello Barretta}, Gloria and Zanello, Piero},
doi = {10.1021/ic9014459},
file = {:home/luca/.local/share/data/Mendeley Ltd./Mendeley Desktop/Downloaded/Albinati et al. – 2010 – Synthesis, structure, and electrochemistry of the dicluster molecular pincer Pt(3)(mu-PBu(t)(2))(3)(CO)(2)(2)(mu-1′,1”’-diethynylbiferrocene).pdf:pdf},
institution = {Dipartimento di Chimica Strutturale e Stereochimica Inorganica, Universit\`{a} di Milano, Via Venezian 21,I-20133 Milano, Italy.},
issn = {1520-510X},
journal = {Inorganic Chemistry},
month = apr,
number = {8},
pages = {3714–3720},
pmid = {20302310},
title = {{Synthesis, structure, and electrochemistry of the dicluster molecular pincer [Pt(3)(mu-PBu(t)(2))(3)(CO)(2)](2)(mu-1′,1”’-diethynylbiferrocene).}},
url = {http://www.ncbi.nlm.nih.gov/pubmed/20302310},
volume = {49},
year = {2010}
}
@article{Accorsi2009,
abstract = {1,10-phenanthroline entails several appealing structural and chemical properties: rigidity, planarity, aromaticity, basicity, chelating capability. This makes it a versatile starting material for synthetic organic, inorganic and supramolecular chemistry. In this tutorial review we examine how the chemical versatility of pristine 1,10-phenanthroline, a weakly fluorescent molecule, has been exploited to design many UV-Vis-NIR luminescent organic derivatives and coordination compounds with transition-metal (Ru(ii), Os(ii), Rh(iii), Cr(iii), Pt(ii), Zn(ii), Cu(i), Ag(i)) and rare-earth (Eu(iii),Tb(iii), Yb(iii), Nd(iii), Er(iii)) cations. They are utilized for many analytical and technological applications.},
author = {Accorsi, Gianluca and Listorti, Andrea and Yoosaf, K and Armaroli, Nicola},
doi = {10.1039/b806408n},
issn = {0306-0012},
journal = {Chemical Society reviews},
language = {en},
month = jun,
number = {6},
pages = {1690–700},
pmid = {19587962},
publisher = {The Royal Society of Chemistry},
title = {1,10-phenanthrolines: versatile building blocks for luminescent molecules, materials and metal complexes.},
url = {http://pubs.rsc.org/en/content/articlehtml/2009/cs/b806408n},
volume = {38},
year = {2009}
}
@book{Zuckerman2009,
abstract = {For the first time the discipline of modern inorganic chemistry has been systematized according to a plan constructed by a council of editorial advisors and consultants, among them three Nobel laureates (E.O. Fischer, H. Taube and G. Wilkinson).Rather than producing a collection of unrelated review articles, the series creates a framework which reflects the creative potential of this scientific discipline. Thus, it stimulates future development by identifying areas which are fruitful for further research. The work is indexed in a unique way by a structured system which maximizes its usefulness to the reader. It augments the organization of the work by providing additional routes of access for specific compounds, reactions and other topics.},
author = {Zuckerman, J. J.},
isbn = {0470145471},
pages = {453},
publisher = {John Wiley \& Sons},
title = {{Inorganic Reactions and Methods, The Formation of Bonds to Elements of Group IVB (C, Si, Ge, Sn, Pb), Part 1 (Google eBook)}},
url = {http://books.google.com/books?id=bWAfgilsYYMC\&pgis=1},
year = {2009}
}
@article{Xu2009,
abstract = {The rates and efficiency of Pt – Ln energy transfer from Pt(2,2′-But2bpy)bis(acetylide) antenna chromophores can be controlled and modulated by changing the spacer between acetylide and 2,2′-bipyridyl/2,2′:6’2”-terpyridyl in the bridging ligands.
The rates and efficiency of Pt – Ln energy transfer from Pt(2,2′-But2bpy)bis(acetylide) antenna chromophores can be controlled and modulated by changing the spacer between acetylide and 2,2′-bipyridyl/2,2′:6’2”-terpyridyl in the bridging ligands.},
author = {Xu, Hai-Bing and Zhang, Li-Yi and Chen, Xiao-Ming and Li, Xiu-Ling and Chen, Zhong-Ning},
doi = {10.1021/cg800866r},
issn = {1528-7483},
journal = {Crystal Growth \& Design},
month = jan,
number = {1},
pages = {569–576},
publisher = {American Chemical Society},
title = {{Modulation of Pt – Ln Energy Transfer in PtLn 2 (Ln = Nd, Er, Yb) Complexes with 2,2′-Bipyridyl/2,2′:6′2′′-Terpyridyl Ethynyl Ligands}},
url = {http://dx.doi.org/10.1021/cg800866r},
volume = {9},
year = {2009}
}
@article{Barbieri2008,
abstract = {Luminescent metal complexes are key materials for several applications such as lighting, analytical probes, and lasers. In many cases compounds based on precious (i.e. platinum group) and rare earth metals are utilized, which are often rather expensive and environmentally problematic. In recent years, interest is growing in luminescent complexes based on less traditional but more abundant and cheaper metal elements. In this scenario compounds of metals with a d10 electronic configuration are playing a prominent role, also thanks to the versatility of their luminescent levels which can be of ligand centred, charge transfer or, in the case of polynuclear compounds, even metal-centred nature. Here we focus on some selected examples of Cu(I), Ag(I), Au(I), Zn(II) and Cd(II) luminescent complexes to suggest some possible routes towards promising and unprecedented emitting materials.},
author = {Barbieri, Andrea and Accorsi, Gianluca and Armaroli, Nicola},
doi = {10.1039/b716650h},
issn = {1359-7345},
journal = {Chemical communications (Cambridge, England)},
language = {en},
month = may,
number = {19},
pages = {2185–93},
pmid = {18463736},
publisher = {The Royal Society of Chemistry},
title = {{Luminescent complexes beyond the platinum group: the d10 avenue.}},
url = {http://pubs.rsc.org/en/content/articlehtml/2008/cc/b716650h},
year = {2008}
}
@book{Balzani2007,
address = {Berlin, Heidelberg},
doi = {10.1007/978-3-540-73349-2},
editor = {Balzani, Vincenzo and Campagna, Sebastiano},
isbn = {978-3-540-73348-5},
publisher = {Springer Berlin Heidelberg},
series = {Topics in Current Chemistry},
title = {{Photochemistry and Photophysics of Coordination Compounds II}},
url = {http://www.springerlink.com/index/10.1007/978-3-540-73349-2},
volume = {281},
year = {2007}
}
@article{Leoni2006,
author = {Leoni, Piero and Marchetti, Lorella and Mohapatra, Swagat Kumar and Ruggeri, Giacomo and Ricci, Lucia},
file = {:home/luca/.local/share/data/Mendeley Ltd./Mendeley Desktop/Downloaded/Leoni et al. – 2006 – Covalent Rigid-Rod Organometallic Polymers with Alternating Transition Metal Clusters and Conjugated Spacers in the Main Chain.pdf:pdf},
number = {c},
pages = {4226–4230},
title = {{Covalent Rigid-Rod Organometallic Polymers with Alternating Transition Metal Clusters and Conjugated Spacers in the Main Chain}},
year = {2006}
}
@article{Senechal-David2006,
abstract = {The development of novel mixed lanthanide-transition-metal (f-d) based supramolecular self-assemblies made from neodymium- and ytterbium-based tetraamide-functionalized cyclen complexes bearing a single 1,10-phenanthroline moiety coordinating to a RuII(bipy)2 (bipy = bipyridine) unit is described. Excitation of the Ru(II) metal-to-ligand charge-transfer band in water gave rise to long-wavelength sensitized emission from the Yb(III) or Nd(III) centers, observed in the near-infrared.},
author = {S\'{e}n\'{e}chal-David, Katell and Pope, Simon J A and Quinn, Susan and Faulkner, Stephen and Gunnlaugsson, Thorfinnur},
doi = {10.1021/ic061706i},
issn = {0020-1669},
journal = {Inorganic chemistry},
keywords = {2,2′-Dipyridyl,2,2′-Dipyridyl: chemistry,Heterocyclic Compounds,Heterocyclic Compounds: chemistry,Lanthanoid Series Elements,Lanthanoid Series Elements: chemistry,Ligands,Luminescence,Molecular Structure,Neodymium,Neodymium: chemistry,Organometallic Compounds,Organometallic Compounds: chemistry,Phenanthrolines,Phenanthrolines: chemistry,Ruthenium,Ruthenium: chemistry,Spectrometry, Fluorescence,Spectroscopy, Near-Infrared,Spectroscopy, Near-Infrared: methods,Ytterbium,Ytterbium: chemistry},
month = dec,
number = {25},
pages = {10040–2},
pmid = {17140205},
publisher = {American Chemical Society},
title = {{Sensitized near-infrared lanthanide luminescence from Nd(III)- and Yb(III)-based cyclen-ruthenium coordination conjugates.}},
url = {http://dx.doi.org/10.1021/ic061706i},
volume = {45},
year = {2006}
}
@article{Biani2005,
author = {Biani, Fabrizia Fabrizi De and Ienco, Andrea and Laschi, Franco and Leoni, Piero and Marchetti, Fabio and Marchetti, Lorella and Mealli, Carlo and Zanello, Piero},
file = {:home/luca/Scrivania/latex\_tesi\_luca/pdf/sintesi esamero.pdf:pdf},
journal = {Journal of the American Chemical Society},
number = {2},
pages = {3076–3089},
title = {{Formation and Characterization of the Hexanuclear Platinum Cluster [Pt 6 (\mu-PBu}},
volume = {6},
year = {2005}
}
@article{Pope2004,
abstract = {Carboxylate-bearing d-transition metal bipyridyls form ternary complexes with seven-coordinate lanthanide centers. The neodymium,- ytterbium-, and erbium-containing complexes exhibit lanthanide-centered emissions sensitized by the MLCT states of the d-block components.},
author = {Pope, Simon J A and Coe, Benjamin J and Faulkner, Stephen and Bichenkova, Elena V and Yu, Xuan and Douglas, Kenneth T},
doi = {10.1021/ja047523h},
issn = {0002-7863},
journal = {Journal of the American Chemical Society},
month = aug,
number = {31},
pages = {9490–1},
pmid = {15291523},
publisher = {American Chemical Society},
title = {{Self-assembly of heterobimetallic d-f hybrid complexes: sensitization of lanthanide luminescence by d-block metal-to-ligand charge-transfer excited states.}},
url = {http://dx.doi.org/10.1021/ja047523h},
volume = {126},
year = {2004}
}
@article{Humphrey2004,
author = {Humphrey, Mark G.},
doi = {10.1002/masy.200450501},
file = {:home/luca/Scaricati/1\_ftp.pdf:pdf},
issn = {1022-1360},
journal = {Macromolecular Symposia},
month = mar,
number = {1},
pages = {1–22},
title = {{Towards oligoclusters– chemistry and properties}},
url = {http://doi.wiley.com/10.1002/masy.200450501},
volume = {209},
year = {2004}
}
@article{Nazeeruddin2003,
abstract = {A new series of iridium(III) mixed ligand complexes TBA[Ir(ppy)(2)(CN)(2)] (1), TBA[Ir(ppy)(2)(NCS)(2)] (2), TBA[Ir(ppy)(2)(NCO)(2)] (3), and [Ir(ppy)(2)(acac)] (4) (ppy = 2-phenylpyridine; acac = acetoylacetonate, TBA = tetrabutylammonium cation) have been developed and fully characterized by UV-vis, emission, IR, NMR, and cyclic voltammetric studies. The lowest energy MLCT transitions are tuned from 463 to 494 nm by tuning the energy of the HOMO levels. These complexes show emission maxima in the blue, green, and yellow region of the visible spectrum and exhibit unprecedented phosphorescence quantum yields, 97 +/- 3\% with an excited-state lifetimes of 1-3 micros in dichloromethane solution at 298 K. The near-unity quantum yields of these complexes are related to an increased energy gap between the triplet emitting state and the deactivating e(g) level that have been achieved by meticulous selection of ligands having strong ligand field strength. Organic light-emitting devices were fabricated using the complex 4 doped into a purified 4,4′-bis(carbazol-9-yl)biphenyl host exhibiting a maximum of the external quantum efficiencies of 13.2\% and a power efficiency of 37 lm/W for the 9 mol \% doped system.},
author = {Nazeeruddin, Md K and Humphry-Baker, R and Berner, D and Rivier, S and Zuppiroli, L and Graetzel, M},
doi = {10.1021/ja021413y},
file = {:home/luca/.local/share/data/Mendeley Ltd./Mendeley Desktop/Downloaded/Nazeeruddin et al. – 2003 – Highly phosphorescence iridium complexes and their application in organic light-emitting devices.pdf:pdf},
issn = {0002-7863},
journal = {Journal of the American Chemical Society},
month = jul,
number = {29},
pages = {8790–7},
pmid = {12862473},
title = {{Highly phosphorescence iridium complexes and their application in organic light-emitting devices.}},
url = {http://www.ncbi.nlm.nih.gov/pubmed/12862473},
volume = {125},
year = {2003}
}
@article{Long2003,
abstract = {Metal alkynyl complexes hold a fascination for synthetic chemists, structural chemists, and materials scientists alike. Harnessing the unique overlap of metal and carbon orbitals is a challenge that can be overcome in many ways and hence, there are many synthetic routes toward M-C=C-bond-forming reactions that utilize a wide variety of transition-metal and alkynyl reagents. Some methods can be widely applied, while others are specific to a particular metal or compound. The linear geometry of the alkynyl unit and its pi-unsaturated character have led to metal alkynyls becoming attractive building blocks for molecular wires and polymeric organometallic materials, which can possess interesting properties, such as optical nonlinearity, luminescence, liquid crystallinity, and electrical conductivity. A unique, multifaceted approach, often combining talents from all three of the above chemical disciplines, has served as a driving force behind the intense research into the development of metal alkynyl sigma complexes, the progress of which, particularly in the last ten years, is summarized in this review.},
author = {Long, Nicholas J and Williams, Charlotte K},
doi = {10.1002/anie.200200537},
issn = {1433-7851},
journal = {Angewandte Chemie (International ed. in English)},
month = jun,
number = {23},
pages = {2586–617},
pmid = {12813734},
title = {{Metal alkynyl sigma complexes: synthesis and materials.}},
url = {http://www.ncbi.nlm.nih.gov/pubmed/12813734},
volume = {42},
year = {2003}
}
@article{Kido2002,
author = {Kido, Junji and Okamoto, Yoshi},
file = {:home/luca/.local/share/data/Mendeley Ltd./Mendeley Desktop/Downloaded/Kido, Okamoto – 2002 – Organo lanthanide metal complexes for electroluminescent materials.pdf:pdf},
issn = {0009-2665},
journal = {Chemical reviews},
month = jun,
number = {6},
pages = {2357–68},
pmid = {12059271},
title = {{Organo lanthanide metal complexes for electroluminescent materials.}},
url = {http://www.ncbi.nlm.nih.gov/pubmed/12059271},
volume = {102},
year = {2002}
}
@article{Lee2002,
abstract = {The Au(I) dimers Au(2)[S(2)P(OR)(2)](2) for R = Me, Et are found to exhibit a structure in which aurophilic interactions yield one-dimensional Au…Au chains with intermolecular contacts (3.09-3.16 A) similar to the Au…Au distances within the dimers (3.10-3.18 A). The dimers are luminescent in the solid state and become brilliantly emissive at low temperatures. At 77 K, Au(2)[S(2)P(OMe)(2)](2) shows multiple emission bands. The two higher energy bands at 415 and 456 nm are assigned to (1)MC and (3)MC on the basis of lifetime measurements (20 ns and 2.16 micros, respectively) and concentration-related effects, while the lower energy band at 560 nm is attributed to a LMCT excited state. In frozen glasses of different solvents, Au(2)[S(2)P(OMe)(2)](2) as well as the Et and n-Pr derivatives exhibit a bright luminescence of different colors and striking thermochromism of the emission.},
author = {Lee, Young-A and McGarrah, James E and Lachicotte, Rene J and Eisenberg, Richard},
file = {:home/luca/.local/share/data/Mendeley Ltd./Mendeley Desktop/Downloaded/Lee et al. – 2002 – Multiple emissions and brilliant white luminescence from gold(I) O,O’-di(alkyl)dithiophosphate dimers.pdf:pdf},
issn = {0002-7863},
journal = {Journal of the American Chemical Society},
month = sep,
number = {36},
pages = {10662–3},
pmid = {12207514},
title = {{Multiple emissions and brilliant white luminescence from gold(I) O,O’-di(alkyl)dithiophosphate dimers.}},
url = {http://www.ncbi.nlm.nih.gov/pubmed/12207514},
volume = {124},
year = {2002}
}
@article{Leoni2001,
author = {Leoni, Piero and Marchetti, Fabio and Marchetti, Lorella and Pasquali, Marco and Quaglierini, Silvia},
doi = {10.1002/1521-3757(20011001)113:19<3729::AID-ANGE3729>3.0.CO;2-M},
file = {:home/luca/.local/share/data/Mendeley Ltd./Mendeley Desktop/Downloaded/Leoni et al. – 2001 – The First Platinum Formyl, a Member of a Series of Hexanuclear Clusters Exhibiting a Rare Structure.pdf:pdf},
issn = {0044-8249},
journal = {Angewandte Chemie},
month = oct,
number = {19},
pages = {3729–3730},
title = {{The First Platinum Formyl, a Member of a Series of Hexanuclear Clusters Exhibiting a Rare Structure}},
url = {http://doi.wiley.com/10.1002/1521-3757\%2820011001\%29113\%3A19\%3C3729\%3A\%3AAID-ANGE3729\%3E3.0.CO\%3B2-M},
volume = {113},
year = {2001}
}
@article{Armaroli2001,
author = {Armaroli, Nicola},
doi = {10.1039/b000703j},
issn = {03060012},
journal = {Chemical Society Reviews},
language = {en},
number = {2},
pages = {113–124},
publisher = {The Royal Society of Chemistry},
title = {{Photoactive mono- and polynuclear Cu(i)–phenanthrolines. A viable alternative to Ru(ii)–polypyridines}},
url = {http://pubs.rsc.org/en/content/articlehtml/2001/cs/b000703j},
volume = {30},
year = {2001}
}
@article{Siemsen2000,
author = {Siemsen, Peter and Livingston, Robert C. and Diederich, Fran\c{c}ois},
doi = {10.1002/1521-3757(20000804)112:15<2740::AID-ANGE2740>3.0.CO;2-F},
issn = {0044-8249},
journal = {Angewandte Chemie},
month = aug,
number = {15},
pages = {2740–2767},
title = {{Acetylenkupplungen: eine leistungsf\”{a}hige Methode f\”{u}r den Aufbau von Molek\”{u}len}},
url = {http://doi.wiley.com/10.1002/1521-3757(20000804)112:15<2740::AID-ANGE2740>3.0.CO;2-F},
volume = {112},
year = {2000}
}
@article{Collin1999,
author = {Collin, Jean-Paul and Dixon, Isabelle M. and Sauvage, Jean-Pierre and Williams, J. a. Gareth and Barigelletti, Francesco and Flamigni, Lucia},
doi = {10.1021/ja9833669},
file = {:home/luca/.local/share/data/Mendeley Ltd./Mendeley Desktop/Downloaded/Collin et al. – 1999 – Synthesis and Photophysical Properties of Iridium(III) Bisterpyridine and Its Homologues a Family of Complexes with a Long-Lived Excited State.pdf:pdf},
issn = {0002-7863},
journal = {Journal of the American Chemical Society},
month = jun,
number = {21},
pages = {5009–5016},
title = {{Synthesis and Photophysical Properties of Iridium(III) Bisterpyridine and Its Homologues: a Family of Complexes with a Long-Lived Excited State}},
url = {http://pubs.acs.org/doi/abs/10.1021/ja9833669},
volume = {121},
year = {1999}
}
@article{Ikegashira1997,
author = {Ikegashira, Kazutaka and Nishihara, Yasushi and Hirabayashi, Kazunori and Mori, Atsunori and Hiyama, Tamejiro},
doi = {10.1039/a701898c},
issn = {13597345},
journal = {Chemical Communications},
language = {en},
number = {11},
pages = {1039–1040},
publisher = {The Royal Society of Chemistry},
title = {{Copper(i) salt promoted homo-coupling reaction of organosilanes}},
url = {http://pubs.rsc.org/en/content/articlehtml/1997/cc/a701898c},
year = {1997}
}
@article{Bruce1997,
abstract = {Recent developments in the chemistry of all-carbon ligands and related molecules include the synthesis and reactions of mono-, bi- and poly-nuclear complexes containing C2, C4 and C8 ligands, as well as of substituted derivatives of allenylidene (:C=C=CH2) and butatrienylidene (:C=C=C=CH2) ligands. The work of the Adelaide group on the pentanuclear ruthenium cluster carbonyl containing a reactive C2 ligand and on the synthesis, chemistry and electrochemistry of a variety of complexes containing C4 and C8 ligands, is described.},
author = {Bruce, Michael I.},
doi = {10.1016/S0010-8545(97)00004-0},
issn = {00108545},
journal = {Coordination Chemistry Reviews},
month = nov,
number = {null},
pages = {91–119},
title = {{Some complexes of all-carbon ligands and related chemistry}},
url = {http://dx.doi.org/10.1016/S0010-8545(97)00004-0},
volume = {166},
year = {1997}
}
@article{Leoni1996,
abstract = {Carbon monoxide (1 atm) quantitatively converts the Pt(II) dinuclear derivative Pt2[mu-P(t-Bu)2]2(H)2[P(t-Bu)2H]2 (1) into the new PtI2PtII triangulo cluster Pt3[mu-P(t-Bu)2]3(H)(CO)2 (2). The 44e- species 2 was characterized by IR and multinuclear NMR spectroscopy and by a single-crystal X-ray diffraction study. Complex 2 is formed through the slow CO-induced reductive elimination of P(t-Bu)2H from 1, affording the intermediate mononuclear Pt(0) carbonyl derivative Pt[P(t-Bu)2H]2(CO)2 (4), which equilibrates with the carbonyl-bridged triangulo derivative Pt3[P(t-Bu)2H]3(mu-CO)3 (5); these are the main products under high pressures of CO. Two alternative mechanisms were examined for the subsequent formation of complex 2, the first being the rapid condensation of complex 4 with unreacted 1 while the second assumes 5 as the direct precursor of 2. Although the first mechanism cannot be conclusively rejected, the second seems the most appropriate, since under high pressures of CO/H2 complex 2 was shown to equilibrate with 5. In the presence of an excess of other phosphines, the carbonylation of 1 yields quantitatively the mononuclear monocarbonyl derivatives Pt(PR3)3(CO) (R3 = Ph3, Et3, t-Bu2H).
Carbon monoxide (1 atm) quantitatively converts the Pt(II) dinuclear derivative Pt2[mu-P(t-Bu)2]2(H)2[P(t-Bu)2H]2 (1) into the new PtI2PtII triangulo cluster Pt3[mu-P(t-Bu)2]3(H)(CO)2 (2). The 44e- species 2 was characterized by IR and multinuclear NMR spectroscopy and by a single-crystal X-ray diffraction study. Complex 2 is formed through the slow CO-induced reductive elimination of P(t-Bu)2H from 1, affording the intermediate mononuclear Pt(0) carbonyl derivative Pt[P(t-Bu)2H]2(CO)2 (4), which equilibrates with the carbonyl-bridged triangulo derivative Pt3[P(t-Bu)2H]3(mu-CO)3 (5); these are the main products under high pressures of CO. Two alternative mechanisms were examined for the subsequent formation of complex 2, the first being the rapid condensation of complex 4 with unreacted 1 while the second assumes 5 as the direct precursor of 2. Although the first mechanism cannot be conclusively rejected, the second seems the most appropriate, since under high pressures of CO/H2 complex 2 was shown to equilibrate with 5. In the presence of an excess of other phosphines, the carbonylation of 1 yields quantitatively the mononuclear monocarbonyl derivatives Pt(PR3)3(CO) (R3 = Ph3, Et3, t-Bu2H).},
author = {Leoni, Piero and Manetti, Silvia and Pasquali, Marco and Albinati, Alberto},
doi = {10.1021/ic9602308},
issn = {0020-1669},
journal = {Inorganic Chemistry},
month = jan,
number = {21},
pages = {6045–6052},
publisher = {American Chemical Society},
title = {{CO-Induced Reductive Elimination of P( t -Bu) 2 H from the Platinum(II) Dinuclear Derivative Pt 2 [$\mu$-P( t -Bu) 2 ] 2 (H) 2 [P( t -Bu) 2 H] 2 , Affording Mononuclear Platinum(0) or Triangulo Triplatinum(I,I,II) Derivatives}},
url = {http://dx.doi.org/10.1021/ic9602308},
volume = {35},
year = {1996}
}
@book{BlasseG.andGrabmaier1995,
address = {New York},
author = {{Blasse, G. and Grabmaier}, B.C},
editor = {Springer-Verlag},
isbn = {3540580190 9783540580195 0387580190 9780387580197},
title = {{Luminescent Materials}},
url = {http://www.worldcat.org/title/luminescent-materials-with-31-tables/oclc/311745503},
year = {1995}
}
@article{Bradford1994,
author = {Bradford, Arleen M. and Kristof, Eva and Rashidi, Mehdi and Yang, Dong-Sheng and Payne, Nicholas C. and Puddephatt, Richard J.},
doi = {10.1021/ic00089a009},
file = {:home/luca/.local/share/data/Mendeley Ltd./Mendeley Desktop/Downloaded/Bradford et al. – 1994 – Isocyanide and Diisocyanide Complexes of a Triplatinum Cluster Fluxionality, Isomerism, Structure, and Bonding.pdf:pdf},
issn = {0020-1669},
journal = {Inorganic Chemistry},
month = may,
number = {11},
pages = {2355–2363},
title = {{Isocyanide and Diisocyanide Complexes of a Triplatinum Cluster: Fluxionality, Isomerism, Structure, and Bonding}},
url = {http://pubs.acs.org/doi/abs/10.1021/ic00089a009},
volume = {33},
year = {1994}
}
@article{States1987,
author = {Lees, Alistair},
file = {:home/luca/.local/share/data/Mendeley Ltd./Mendeley Desktop/Downloaded/States et al. – 1987 – Luminescence Properties of Organometallic Complexes.pdf:pdf},
journal = {Chemical reviews},
pages = {711–743},
title = {{Luminescence Properties of Organometallic Complexes}},
volume = {87},
year = {1987}
}
@article{Sonogashira1977,
author = {Sonogashira, K. and Takahashi, S. and Hagihara, N.},
doi = {10.1021/ma60058a037},
issn = {0024-9297},
journal = {Macromolecules},
month = jul,
number = {4},
pages = {879–880},
publisher = {American Chemical Society},
title = {{A New Extended Chain Polymer, Poly[trans-bis(tri-n-butylphosphine)platinum 1,4-butadiynediyl]}},
url = {http://dx.doi.org/10.1021/ma60058a037},
volume = {10},
year = {1977}
}
@article{Kim1970,
author = {Kim, P.J. and Masai, H. and Sonogashira, K. and Hagihara, N.},
doi = {10.1016/0020-1650(70)80337-3},
issn = {00201650},
journal = {Inorganic and Nuclear Chemistry Letters},
month = feb,
number = {2},
pages = {181–185},
title = {{Preparations of $\alpha$, $\omega$-bis-nickel-polyacetylenes}},
url = {http://dx.doi.org/10.1016/0020-1650(70)80337-3},
volume = {6},
year = {1970}
}
@misc{Cotton1968,
author = {Cotton, A},
booktitle = {Inorganic Chemistry},
file = {:home/luca/.local/share/data/Mendeley Ltd./Mendeley Desktop/Downloaded/Cotton – 1968 – Metal-Metal Bonding in Re2XsI2- Ions and Other Metal Atom Clusters1.pdf:pdf},
number = {1965},
pages = {1964–1966},
title = {{Metal-Metal Bonding in [Re2XsI2- Ions and Other Metal Atom Clusters1}},
volume = {326},
year = {1968}
}
@article{Cotton1965,
author = {Cotton, F. A. and Lippard, S. J.},
doi = {10.1021/ic50023a013},
file = {:home/luca/.local/share/data/Mendeley Ltd./Mendeley Desktop/Downloaded/Cotton, Lippard – 1965 – The Preparation and Characterization of Compounds Containing both Hexabromorhenate(IV) and the Trirhenium Non abromide Group.html:html},
issn = {0020-1669},
journal = {Inorganic Chemistry},
month = jan,
number = {1},
pages = {59–65},
publisher = {American Chemical Society},
title = {{The Preparation and Characterization of Compounds Containing both Hexabromorhenate(IV) and the Trirhenium Non abromide Group}},
url = {http://dx.doi.org/10.1021/ic50023a013},
volume = {4},
year = {1965}
}
@article{Cotton1964,
author = {Cotton, F. A.},
doi = {10.1021/ic50019a003},
file = {:home/luca/.local/share/data/Mendeley Ltd./Mendeley Desktop/Downloaded/Cotton – 1964 – Metal Atom Clusters in Oxide Systems.html:html},
issn = {0020-1669},
journal = {Inorganic Chemistry},
month = sep,
number = {9},
pages = {1217–1220},
publisher = {American Chemical Society},
title = {{Metal Atom Clusters in Oxide Systems}},
url = {http://dx.doi.org/10.1021/ic50019a003},
volume = {3},
year = {1964}
}
@article{Flu-1964,
author = {Flu-, Hydrogen},
file = {:home/luca/.local/share/data/Mendeley Ltd./Mendeley Desktop/Downloaded/Flu- – 1964 – Metal Atom Clusters in Oxide Systems1.pdf:pdf},
number = {9},
pages = {10–13},
title = {{Metal Atom Clusters in Oxide Systems1}},
volume = {3},
year = {1964}
}
@article{Bertrand1963,
author = {Bertrand, J. A. and Cotton, F. A. and Dollase, W. A.},
doi = {10.1021/ja00892a029},
file = {:home/luca/.local/share/data/Mendeley Ltd./Mendeley Desktop/Downloaded/Bertrand, Cotton, Dollase – 1963 – The Metal-Metal Bonded, Polynuclear Complex Anion in CsReCl4.html:html},
issn = {0002-7863},
journal = {J. Am. Chem. Soc.},
number = {9},
pages = {1349–1350},
publisher = {American Chemical Society},
title = {{The Metal-Metal Bonded, Polynuclear Complex Anion in CsReCl4}},
url = {http://dx.doi.org/10.1021/ja00892a029},
volume = {85},
year = {1963}
}
@article{Cottos1963,
author = {Cottos, F A and Dollase, W A},
file = {:home/luca/.local/share/data/Mendeley Ltd./Mendeley Desktop/Downloaded/Cottos, Dollase – 1963 – Dodecachlorotrirhenate(III),.pdf:pdf},
number = {9},
pages = {1166–1171},
title = {{Dodecachlorotrirhenate(III),}},
year = {1963}
}
@article{Bertrand1963a,
author = {Bertrand, J. A. and Cotton, F. A. and Dollase, W. A.},
doi = {10.1021/ic50010a019},
file = {:home/luca/.local/share/data/Mendeley Ltd./Mendeley Desktop/Downloaded/Bertrand, Cotton, Dollase – 1963 – The Crystal Structure of Cesium Dodecachlorotrirhenate-(III), a Compound with a New Type of Metal Atom Cluster.html:html},
issn = {0020-1669},
journal = {Inorganic Chemistry},
month = dec,
number = {6},
pages = {1166–1171},
publisher = {American Chemical Society},
title = {{The Crystal Structure of Cesium Dodecachlorotrirhenate-(III), a Compound with a New Type of Metal Atom Cluster}},
url = {http://dx.doi.org/10.1021/ic50010a019},
volume = {2},
year = {1963}
}
@article{Crosby1961,
author = {Crosby, G. a. and Whan, R. E. and Alire, R. M.},
doi = {10.1063/1.1731670},
file = {:home/luca/.local/share/data/Mendeley Ltd./Mendeley Desktop/Downloaded/Crosby, Whan, Alire – 1961 – Intramolecular Energy Transfer in Rare Earth Chelates. Role of the Triplet State.pdf:pdf},
issn = {00219606},
journal = {The Journal of Chemical Physics},
number = {3},
pages = {743},
title = {{Intramolecular Energy Transfer in Rare Earth Chelates. Role of the Triplet State}},
url = {http://link.aip.org/link/JCPSA6/v34/i3/p743/s1\&Agg=doi},
volume = {34},
year = {1961}
}
@article{Armitage1952,
author = {Armitage, J. B. and Jones, E. R. H. and Whiting, M. C.},
doi = {10.1039/jr9520002014},
issn = {0368-1769},
journal = {Journal of the Chemical Society (Resumed)},
language = {en},
pages = {2014},
publisher = {The Royal Society of Chemistry},
title = {{373. Researches on acetylenic compounds. Part XXXVII. The synthesis of conjugated tetra-acetylenic compounds}},
url = {http://pubs.rsc.org/en/content/articlehtml/1952/jr/jr9520002014},
year = {1952}
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@article{Leoni2003,
author = {Leoni, Piero and Marchetti, Fabio and Marchetti, Lorella and Pasquali, Marco},
doi = {10.1039/b307003d},
isbn = {10.1039/B307003D},
issn = {1359-7345},
journal = {Chemical Communications},
language = {en},
number = {18},
pages = {2372},
publisher = {The Royal Society of Chemistry},
title = {{Trinuclear and hexanuclear platinum clusters as building blocks for organometallic one-dimensional structuresElectronic supplementary information (ESI) available: experimental procedures and characterization data. See http://www.rsc.org/suppdata/cc/b3/b30}},
url = {http://pubs.rsc.org/en/content/articlehtml/2003/cc/b307003d},
year = {2003}
}